Material Safety Data Sheet   RI-77AA

 

     OSHA Hazard Communication Standard:  29 CFR 1910-1200 Standard must be consulted for specific requirements.

Note:  Read Material Safety Data Sheets before using product.

 

 

1  PRODUCT INFORMATION

 

Identity:  RI-77AA

Manufacturer’s Name:                                  ROAN Industries, Inc.

                                                                        100 Chet Burleson Road

                                                                        Bakersville, NC  28705

 

Emergency Telephone Number:  CHEMTREC (800) 424-9300

Telephone Number for Information: (828) 688-5888 or (610) 759-4234

Date Revised:  May 21, 2008

 

2  HAZARDOUS INGREDIENTS/IDENTITY INFORMATION

 

Common Name/Chemical Identity:                                            OSHA PEL    ACGIH TLV        OTHER LIMITS

      A variable blend of the following ingredients:                                                                                               

      Acetic Acid 64-19-7                                                                   10ppm TWA    10ppm TWA            15ppmSTEL

        Ethylene Glycol 107-21-1                                                            50ppm (ceiling)      100mg / m3 (ceiling)   See Below

      Diethylene Glycol 111-46-6                                                            N.I.F.                N.I.F.                      N.I.F.     

      Triethylene Glycol 112-27-6                                                           N.I.F.                N.I.F.                      N.I.F.

      Tetraethylene Glycol 112-60-7                                                       N.I.F.                N.I.F.                      N.I.F.

      Triethanolamine 102-71-6                                                              N.I.F.               5 mg/m3TWA8          N.I.F.

      Diethanolamine 111-42-2                                                            15mg/m3TWA    2mg/m3TWA8      See Below

      Monoethanolamine 141-43-5                                                         N.I.F.                3ppm                       N.I.F.

      Oxirane, reaction products with Ammonia and

      distillation residues 68953-70-8                                                      N.I.F.                 N.I.F.                      N.I.F.            N,N,N’-tris(2-hydroxyethyl)

      Ethylenediamine 060487-26-5                                                        N.I.F.                N.I.F.                      N.I.F.     

      Acetic anhydride 108-24-7                                                        5ppm TWA      5ppm TWA                   N.I.F.

      Acetone 67-64-1                                                                        1000ppm         500ppmTWA               N.I.F.

        Water 7732-18-5                                                                           N.I.F.                N.I.F.                      N.I.F.

      Pentaethylene glycol 4792-15-8                                                      N.I.F.                N.I.F.                      N.I.F.

               

 

 

 

Section 313 Supplier Notification:  This product can contain up to the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372).

CAS#                                                      Chemical Name                                   Max % by Weight

107-21-1                                                 Ethylene Glycol                                  10%

111-42-2                                                 Diethanolamine                                   5%  

This information must be included in all MSDSs that are copied and distributed for this material.

 

Material Safety Data Sheet   RI-77AA

 

3  PHYSICAL/CHEMICAL CHARACTERISTICS

 

Boiling Point:  100-165° C / 212-329° F             Specific Gravity (H20=1) At 25° C:  1.11 - 1.16

Vapor Pressure:  N.I.F.                                       Melting Point:  N.I.F.          

Vapor Density:  Over 1.0                                     Evaporation Rate (Butyl Acetate=1):  N.I.F.

Solubility in Water:  Miscible

Appearance and Odor:  Dark amber liquid with characteristic odor.

 

4  FIRE AND EXPLOSION HAZARD DATA

 

Flash Point (Method Used):  Open Cup 160° C / 320° F COC     Flammable Limits:  LEL: N.I.F.   UEL: N.I.F.

Extinguishing Media:  Water spray, foam, dry chemical or carbon dioxide.

Special Fire Fighting Procedures:

      Fight fire from upwind position if possible.

      Use positive pressure breathing apparatus.

      Use complete protective clothing as needed.

Unusual Fire and Explosion Hazards:

      Some foaming can take place when fighting fire.

      Will burn under right conditions of heat and oxygen supply.

      Filled drums in the area of the fire should be kept cool by a water spray.

 

5  REACTIVITY DATA

 

Stability:  Stable

Conditions to Avoid:  Strong oxidizers, excessive heat, sparks, or open fire.

Incompatibility:  Strong oxidizers, acids, bases, nitrites, certain metals, chromium trioxide, sodium peroxide, acrolein, silver chlorate, ammonia dichromate, sodium chlorite, halogenated organic solvents.

Hazardous Decomposition or Byproducts:  Oxides of carbon, nitrogen, irritating aldehydes, and ketones.

Hazardous Polymerization:  Will not occur.

 

6       HEALTH HAZARD DATA

 

Route of Entry: 

      Eyes, Skin, Inhalation, and Ingestion

Health Hazards: 

      Eyes:  May cause severe irritation of eyes.  May cause corneal injury.             

Skin:  Prolonged or repeated exposure may cause irritation, redness, and swelling.

 

 

 

 

 

 

 

Material Safety Data Sheet   RI-77AA

 

6  HEALTH HAZARD DATA (Continued)

Inhalation:  High concentrations can cause nose, throat and lung irritation. Also headache, nausea, and drowsiness. 

Ingestion:  Can cause nausea, abdominal discomfort, diarrhea, drowsiness, dizziness, loss of

      coordination, and fatigue.  Can be toxic and affect the kidneys and liver.  Aspiration hazard if swallowed

      Contains Ethylene Glycol, which may cause birth defects based on animal data.

Carcinogenicity:  NTP?  N.I.F.          IARC Monographs?  N.I.F.            OSHA Regulated?  N.I.F.

Signs and Symptoms of Exposure: 

      Eyes:  Irritation and redness.

      Skin:  May cause irritation especially if prolonged or repeated exposure.

      Inhalation:  Irritation of respiratory tract, headache, nausea, and drowsiness.

      Ingestion:  Irritation of digestive tract, drowsiness, dizziness, loss of coordination, fatigue, nausea, and         confusion. Increased heart rate, decreased blood pressure, and unconsciousness.

Medical Conditions Generally Aggravated by Exposure:

      Repeated overexposure of pre-existing skin conditions, eye problems, lung, liver and kidney disorders.

Emergency and First Aid Procedures:

Eyes:  Flush with plenty of water for at least 15 minutes, forcibly holding eyelids open.  Contact a physician. 

Skin:  Remove contaminated clothing and wash skin with soap and water for several minutes. Contact a physician if irritation develops or persists.

      Inhalation:  Move person into fresh air.  Get medical attention.  Use artificial respiration and/or oxygen, if required.

      Ingestion:  Give two glasses of water (16oz.).  Do not induce vomiting. Contact a physician.

      Never give anything by mouth to an unconscious person.

      In an emergency or if in doubt, contact a physician.

 

7  PRECAUTIONS FOR SAFE HANDLING AND USE

 

Steps To Be Taken in Case Material is Released or Spilled:

      Contain the spill.  Eliminate ignition sources.  Avoid eye and skin contact.  Avoid breathing vapor.

      Ventilate area.  Use non-combustible absorbent materials; place absorbed spill into labeled airtight drums.

Keep spill out of drains, sewers and waterways. Wear personal protective clothing and equipment including appropriate respiratory protection.

Waste Disposal Method:  Dispose all waste in accordance with Federal, State and Local regulations.

Precautions To Be Taken in Handling and Storing:

      Store in tightly closed containers in a cool area away from heat and flames.

      Use with adequate ventilation and proper grounding of all transfer equipment.

      Avoid breathing of vapors and mist.

      Avoid contact with eyes, skin, or clothing.

      Use proper personal protective equipment when needed.

        Launder contaminated clothing before re-use. 

      Store away from incompatible materials.

 

 

 

Material Safety Data Sheet   RI-77AA

 

8  CONTROL MEASURES

Respiratory Protection (Specify Type):

      When required for certain operations, use an approved air -purifying respirator. (NIOSH Approved)

Ventilation

      Local Exhaust:  Recommended when appropriate to control employee exposure.

      Mechanical (General):  Use in addition to local exhaust if required.

Protective Gloves:  Use chemical resistant gloves.  

Eye Protection:  Use chemical safety goggles.

Other Protective Clothing or Equipment:  Impervious apron or other protective clothing as required.

Work/Hygienic Practices:  Wash skin thoroughly with soap and water after handling and before eating.

      Remove contaminated clothing and launder before reuse.

Engineering Controls:  Emergency shower and eyewash facility should be in close proximity.

 

9 TRANSPORTATION INFORMATION

 

Proper Shipping Name:  N/A

UN/NA Number:  N/A

Domestic Hazard Class:  Non-hazardous

Surface Freight Classification:  Liquid Cement Grinding Aid

Label/Placard Required:  N/A

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

DISCLAIMER:  INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED ON DATA BELIEVED TO BE CORRECT.  HOWEVER, NO GUARANTEE OR WARRANTY IS IMPLIED OR MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN.